特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,22-27(1995) |
固体酸素の96GPaでの構造転移と金属化:分子金属の可能性 High-Pressure Structural Transition of Oxygen at 96 GPa: Possibility of Molecular Metal |
赤浜 裕一 川村 春樹 Yuichi AKAHAMA, Haruki KAWAMURA |
By using high-energy and high-brilliant synchrotron radiation
source in ESRF and PF, an angle-dispersive
powder x-ray diffraction study on oxygen
has been carried out up to 117 GPa at room
temperature. A new high-pressure structural
transition was observed at 96 GPa and explained
as an isostructural one with a discontinuous
change of lattice constants in a monoclinic
cell. Metallization for oxygen reported by
S. Desgreniers et al. [1] is ascribed to
the transition. [oxygen, high-pressure, phase transition, synchrotron radiation, molecular metal, x-ray diffraction] |
〒678-1297 兵庫県赤穂郡上郡町光都3-2-1 姫路工業大学理学部物質科学科 Department of Material Science, Faculty of Science, Himeji Institute of Technology, 3-2-1, Kouto, Kamigohri, Hyogo 678-12 |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,28-34(1995) |
放射光粉末角度分散回折法によるビスマス高圧相の構造解析 Structure Determination of High Pressure Phases of Bismuth by Synchrotron Radiation Angle Dispersive Powder Diffraction |
陳 久華1 岩崎 博2 亀卦川 卓美3 Chen Jiuhua, Hiroshi IWASAKI, Takumi KIKEGAWA |
High quality diffraction data of high pressure
phases of bismuth, BiV, BiV' and BiW,
were obtained by using the high energy Synchrotron
Radiation. Based on the observed diffraction
data, crystal structures of these phases
have been solved as, BiV: tetragonal structure
with unit cell parameters of a=0.8680±0.0005nm
and c=0.4248±0.0003nm at 3.2 GPa, BiV':
the same structure as BiV, and BiW: monoclinic
structure with unit cell parameters of a=0.6463±0.0005nm,
b=0.6460±0.0005nm, c=0.6582±0.0006nm and
γ=118.84±0.05° at 3.9 GPa and 503 K. The
relations of atomic arrangements between
BiV and BiX, BiW and BiX are discussed. [in-situ X-ray diffraction, angle dispersive method, crystal structure, bismuth] |
1Center for High Pressure Research and Department
of Earth and Space Sciences, State University
of New York at Stony Brook, Stony Brook,
NY 11794-2100, USA. 2〒525-8577 草津市野路東1-1-1 立命館大学理工学部光工学科 Faculty of Science and Engineering, Ritsumeikan University,Nogihigashi 1-1-1, Kusatsu, Shiga 525-8577 3〒305-0801 つくば市大穂1-1 高エネルギー Photon Factory, National Laboratory for High Energy Physics, 1-1 Oho, Tsukuba, Ibaraki 305-0801. |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,35-41(1995) |
ケイ酸塩・ゲルマン酸塩の圧力誘起非晶質化 Pressure-induced Amorphization of Silicates and Germanates |
永井隆哉 Takaya NAGAI |
Pressure-induced amorphization is a kinetically
hindered phenomenon. The amorphization has
been a topic not only in the field of high
pressure physics but also in the field of
earth science for the last decade. The amorphization
of minerals will play an important role to
understand the mechanism of deep-forcus earthquakes
in the subduction zone, the rheological properties
of the slub and the recycling water in the
mantle, and so on. In this article, the pressure-induced
amorphization of silicates and germanates
will be reviewed from the view point of the
crystal structures and our resent experiments
using the synchrotron radiation will be introduced. [amorphization, silicates, germanates, coordination change, XAFS] |
〒560-0043 大阪府豊中市待兼山町1-1 大阪大学大学院理学研究科宇宙地球科学専攻 Department of Space and Earth Science, Osaka University, 1-16 Machikaneyama, Toyonaka, Osaka 560-0043 |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,42-48(1995) |
高圧下のXAFS XAFS Studies under Pressure |
片山芳則 Yoshinori KATAYAMA |
Recent advance in X-ray Absorption Fine Structure(XAFS)
study under pressure is reviewed. After a
brief introduction to XAFS and its applications
to high-pressure studies, recent development
of XAFS measurements under pressure at the
Photon Factory is presented. We successfully
obtained X-ray absorption spectra at pressures
up to 10 GPa and temperatures up to 700 ℃
using a multi-anvil type apparatus, MAX90.
Results of our studies on crystalline selenium,
amorphous selenium and isolated selenium
chains are presented. [high pressure, XAFS, EXAFS, synchrotron radiation, crystal structure, amorphous, selenium] |
〒679-5148 兵庫県佐用郡三日月町光都1-1-1 日本原子力研究所関西研究所放射光利用研究部 |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,49-54(1995) |
メスバウアー効果による研究 Mossbauer Spectroscopic Study |
那須 三郎 Saburo NASU |
Mossbauer spectroscopic studies of pressure-induced
transition from antiferro- to ferro-magnetism
of Fe in SrFeO3 at 74 GPa has been performed using a diamond
anvil cell (DAC) and the nuclear forward
scattering of synchrotron radiation under
external magnetic field. Brief description
of the principles in Mossbauer spectroscopy
using a radio-isotope g-ray source has been
given. The basic concept and a method to
detect the nuclear forward scattering with
synchrotron radiation have been explained
briefly. [DAC, 57Fe Mossbauer spectroscopy, iron-oxides, SrFeO3, hyperfine interaction parameters, nuclear forward scattering, synchrotron radiation, pressure-induced antiferro-to-ferromagnetic transition] |
〒560-8531 豊中市待兼山町1-3 大阪大学大学院基礎工学研究科物理系専攻物性物理化学分野 Department of Material Physics, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka 560 |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,55-61(1995) |
放射型スリットによる角度分散回折測定法 Angle-dispersive Diffraction Measurement Using a Radial Slit |
矢尾板 憲一 Kenichi YAOITA |
A newly developed angle-dispersive diffraction
measurement system for high-pressure experiments
is reviewed. This system has an optical
device called Radial Slit, which is consisted
with multiple collimators aligned radially.
This eliminates the diffraction from the
materials surrounding the sample, so that
we can measure diffraction from samples in
a multi-anvil press by an imaging-plate (IP).
Performance of the Radial Slit has been evaluated
to be satisfactory, and diffraction patterns
of crystal corundum and glassy silica have
successfully been obtained using this system. [angle-dispersive, x-ray diffraction, multi-anvil press, radial slit, imaging plate, MAX90, synchrotron radiation, high pressure] |
〒196-8666 昭島市松原町3-9-12 理学電機(株)応用技術センター東京分析センター |
特集-圧力誘起相転移の研究への放射光の応用- Rev. High Pressure Sci. Technol. 4-1,62-67(1995) |
赤外スペクトルによる微粒子の相転移 Phase Transition of Microcrystals by Infrared Spectroscopy |
難波 孝夫 Takao NANBA |
In this article, the important role of the
synchrotron radiation in the field
of spectroscopic
study under high pressure up to 20
GPa in
the infrared region is emphasized.
As a typical
example of such experiments which became
possible to perform, the experiment
on the
surface phonon of CdS microcrystals
under
high pressure using a DAC is presented.
Through
an analysis of the energy shifts of
the surface
phonon with pressure, we found that
the magnitude
of the critical pressure indicating
a structural
phase transition in the microcrystal
differs
from that for the bulk. [synchrotron radiation, phase transition, surface phonon, microcrystal, CdS, DAC, far-infrared spectroscopy ] |
〒657-8501 神戸市灘区六甲台町1-1 神戸大学大学院自然科学研究科 Kobe University, Rokkodai-cho1-1, Nada-ku, Kobe 657-8501 |
解説 Rev. High Pressure Sci. Technol. 4-1,68-75(1995) |
ダイヤモンド燒結体 Diamond Compact |
上原 一仁 Kazuhito UEHARA |
Diamond compact (polycrystalline Diamond:
PCD) is the material produced by sintering
diamond powder under ultra-high pressure
and high temperature conditions. It has been
widely used as cutting tools, wire drawing
dies, rock drilling bits and wear-resistant
parts. This paper describes in outline the kinds and the applications of commercial PCD, the manufacturing process, sintering mechanism and cutting performances of PCD for cutting tools and the relation between PCD and recent CVD diamond tools. [diamond compact, PCD, ultra-high pressure, cutting tools, CVD diamond] |
〒970-1144 いわき市好間工業団地11-1 東芝タンガロイ(株)いわき工場 Toshiba Tungaloy Co., Ltd., |
解説 Rev. High Pressure Sci. Technol. 4-1,76-83(1995) |
高圧を利用した複素環化合物の合成 The Synthesis of Heterocyclic Compounds under High Pressure |
田口 洋一 安本 昌彦 Yoichi TAGUCHI, Masahiko YASUMOTO |
Heterocyclic compounds are used now in various
fields, and many reports have been
published
on the synthesis of these compounds
every
year. This article deals with the studies
in our group on the synthesis of heterocyclic
compounds including sulfur or nitrogen
under
high pressure. Nitriles, cianamides,
carbon
disulfide, isocyanates, and isothiocyanates
were good reagents for high pressure
synthesis
and led to some novel reactions different
from those at ordinary pressure. The
reactions
of these reagents under high pressure
have
a possibility of developing new synthetic
methods of heterocyclic compounds. [heterocyclic compounds, cyanides, cyanamides, carbon disulfide, isocyanates, isothiocyanates] |
〒305-8565 つくば市東1-1 物質工学工業技術研究所有機合成化学部有機構造相関研究室 National Institute of Materials and Chemical Research,Higashi 1-1, Tsukuba 305-8565 |
〒606-0805
京都市左京区下鴨森本町 15 (財)生産開発科学研究所内
日本高圧力学会事務局
Tel (075)721-0376 Fax (075)723-9629
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